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A one-dimensional numerical model for a Cu-zeolite SCR catalyst has been developed. The model is based on kinetics developed from laboratory microreactor data for the various NH₃-NOX reactions, as well as for NH₃ oxidation. The kinetic scheme used is discussed and evidence for it presented. The model is capable of predicting the conversion of NO and NO₂, NH₃ slip and the formation of N₂O, as well as effects associated with NH₃ storage and desorption. To obtain a good prediction of catalyst temperature during cold start tests, it was found necessary to include storage and desorption of H₂O in the model; storage of H₂O is associated with a sizable exotherm and the subsequent desorption of this water produces a correspondingly large endotherm.

The aftertreatment challenge in the non-road market is making the same system work and fit not just in one machine, but in hundreds of different machines, some of which can be used for many different purposes. This huge diversity of applications and the relatively small unit numbers for each application, coupled with the rapid introduction of new standards and the very high performance needed from the engines and machines, requires a sophisticated approach to product development. Furthermore, as emissions requirements become ever more stringent, designing a system to meet the legislation subject to packaging and cost constraints becomes progressively more difficult. This is further exacerbated by increasing system complexity, where more than one technology may be required to control all the legislated pollutants and/or an active control strategy is involved. Also a very high degree of component integration is required.

The effective matching of the exhaust mufflers and engines is an important measure to reduce the noise emission of running vehicles. Currently, the matching is based mainly on the steady state performance of engine. The muffler's influence on a vehicle's noise emission and sound quality under different running conditions is not generally considered. A comprehensive performance evaluation method is proposed to describe the muffler's influence on a commercial vehicle's noise emission, sound quality and exhaust back pressure under multiple working conditions. The weighted insertion loss and linearity coefficient were defined based on the test data of the exhaust noise under different engine loads and speeds. A comprehensive performance evaluation method was defined from the test data analysis of engine exhaust noise with different mufflers. Finally, the simulation results of the exhaust noise of a vehicle with different mufflers were compared with test data.

The fuel reforming technology has been extensively investigated as a way to produce hydrogen on-board a vehicle that can be utilized in internal combustion engines, fuel cells and aftertreatment technologies. Maximization of H2 production in the reforming process can be achieved when there is optimized water (steam) addition for the different reforming temperatures. A way to increase the already available water quantity on-board a vehicle (i.e. exhaust gas water content) is by using emulsified fuel (e.g. water-diesel blend). This study presents the effect of an emulsified diesel fuel (a blend of water and diesel fuel with an organic surfactant to make the mixture stable) on combustion in conjunction with exhaust gas assisted fuel reforming on a compression ignition engine. No engine modification was required to carry out these tests. The emulsified diesel fuel consisted of about 80% (mass basis) of conventional ultra low sulphur diesel (ULSD) fuel and fixed water content.

Biofuels development and specification are currently driven by the engine (mainly gasoline- and diesel-type) technology, existing fossil fuel specification and availability of feedstock. The ability to use biofuels with conventional fuels without jeopardising the standard fuel specifications is a very effective means for the implementation of these fuels. In this work the effect of dual fuelling with in-cylinder injected ULSD fuel or synthetic second generation biofuels (a Gas-To-Liquid GTL fuel as a surrogate of these biofuels as its composition, specifications and production process are very similar to second generation biofuels) and with inlet port injected bioethanol on the engine performance and emissions were investigated. The introduction of anhydrous bioethanol improved the NOx and smoke emissions, but increased total hydrocarbons and carbon monoxide.

The paper presents analysis of performance and emission characteristics of a common rail diesel engine operating with RME, with and without EGR. In both cases, the RME fuel was pre-heated in a heat exchanger to control its temperature before being pumped to the common rail. The studied parameters include the in-cylinder pressure history, rate of heat release, mass fraction burned, and exhaust emissions. The results show that when the fuel temperature increases and the engine is operated without EGR, the brake specific fuel consumption (bsfc) decreases, engine efficiency increases and NOx emission slightly decreases. However, when EGR is used while fuel temperature is increased, the bsfc and engine efficiency is independent of fuel temperature while NOx slightly increases.

Limits on the total future potential of biodiesel fuel due to the availability of raw materials mean that ambitious 20% fuel replacement targets will need to be met by the use of both first and next generation biodiesel fuels. The use of higher percentage biodiesel blends requires engine recalibration, as it affects engine performance, combustion patterns and emissions. Previous work has shown that the combustion of 50:50 blends of biodiesel fuels (first generation RME and next generation synthetic fuel) can give diesel fuel-like performance (i.e. in-cylinder pressure, fuel injection and heat release patterns). This means engine recalibration can be avoided, plus a reduction in all the regulated emissions. Using a 30% biodiesel blend (with different first and next generation proportions) mixed with Diesel may be a more realistic future fuel.

The use of catalyzed diesel particulate filter (CDPF) systems in light duty diesel (LDD) vehicles is becoming increasingly common. The primary functions of the system are to remove carbon monoxide (CO) and hydrocarbons (HC) from the vehicle exhaust stream, while simultaneously reducing the level of particulate matter (PM) emissions to ambient background levels. These systems can comprise either a separate diesel oxidation catalyst (DOC) and a downstream CDPF, or a single unit CDPF with the DOC functions incorporated within the CDPF. The single CDPF unit provides higher regeneration efficiency as it is located nearer to the engine and also cost benefits, as only a single unit is required compared to the alternative separate DOC and CDPF arrangement. A model describing the performance of the single unit CDPF for emissions control has been developed, with particular emphasis on achieving predictions of the CO and HC emissions over transient vehicle drive cycles.

A prototype catalyst has been developed and integrated within the aftertreatment exhaust system to control the HC, CO, PM and NOx emissions from diesel exhaust gas. The catalyst activity in removing HC and nano-particles was examined with exhaust gas from a diesel engine operating on biodiesel - Rapeseed Methyl Ester (RME). The tests were carried out at steady-state conditions for short periods of time, thus catalyst tolerance to sulphur was not examined. The prototype catalyst reduced the amount of hydrocarbons (HC) and the total PM. The quantity of particulate with electrical mobility diameter in nucleation mode size < 10nm, was significantly reduced over the catalyst. Moreover, it was observed that the use of EGR (20% vol.) for the biodiesel fuelled engine significantly increases the particle concentration in the accumulation mode with simultaneous reduction in the particle concentration in the nuclei mode.

The effects of variable intake-valve-timing on the gas exchange process and performance of a 4-valve direct-injection HCCI engine were computationally investigated using a 1D gas dynamics engine cycle simulation code. A non-typical strategy to actuate the pair of intake valves was examined; whereby each valve was assumed to be actuated independently at different timing. Using such an intake valves strategy, the obtained results showed a considerable improvement of the engine parameters such as load and charging efficiency as compared with the typical identical intake valve pair timings case. Additional benefits of minimizing pumping losses and improving the fuel economy were demonstrated with the use of the non-simultaneous actuation of the intake valve pair having the opening timing of the early intake valve coupled with a symmetric degree of crank angle for the timing of exhaust valve closing.

Homogeneous Charge Compression Ignition (HCCI) has emerged as a promising technology for reduction of exhaust emissions and improvement of fuel economy of internal combustion engines. There are generally two proposed methods of realizing the HCCI operation. The first is through the control of gas temperature in the cylinder and the second is through the control of chemical reactivity of the fuel and air mixture. EGR trapping, i.e., recycling a large quantity of hot burned gases by using special valve-train events (e.g. negative valve overlap), seems to be practical for many engine configurations and can be combined with any of the other HCCI enabling technologies. While this method has been widely researched, it is understood that the operating window of the HCCI engine with negative valve overlap is constrained, and the upper and lower load boundaries are greatly affected by the in-cylinder temperature.

This paper presents a computational investigation of the in-cylinder charge characteristics within a motored 4-valve direct injection HCCI engine cylinder with applied negative valve overlapping. Non-typical intake valve strategy was investigated; whereby the pair of intake valves was assumed to follow the same low-lift short-duration valve-lift profile but actuated at different timings. The phase of intake-valve-opening relative to that of exhaust-valve-closing was optimized in terms of pumping losses. The flow fields generated with such an intake valve strategy were compared to those produced in the same engine cylinder but with typical early and late intake-valve-timing. The computational results of such an approach showed modifications in the in-cylinder swirl and tumble motions during the intake and compression strokes.

Producing on-board the hydrogen that is to be used as supplementary fuel by exhaust gas reforming of gasoline shows encouraging results. Extensive research has been done at the University of Birmingham towards on board generation of hydrogen-rich gaseous fuel. Exhaust gas reforming which utilizes water vapor and enthalpy from the hot engine exhaust gas was applied using a compact system of a fuel reformer reactor integrated with the three way catalytic converter (TWC). Such system can be fitted in the limited space close to the engine. The device has been designed and built in concentric shape with the catalytic converter as a core and the reformer in an annular shape outside, to best utilize the waste heat from the catalytic converter. It requires very little extra space beyond the baseline catalytic converter.

The hydrocarbon-SCR activity of a silver catalyst has been examined using actual exhaust gas from a diesel engine, without any fuel being added to the reactor inlet. This work is a further step in the development of an active lean-NOx catalyst for aftertreatment of exhaust streams that contain an excess of hydrocarbon relative to NOx. The engine tests follow on from laboratory studies, in which the activity was related to the composition and formulation of the catalyst, the concentration and speciation of the hydrocarbon reductants, and the composition and temperature of simulated exhaust gas. In all the tests described here, the exhaust gas has been provided by an engine operating on ultra-low sulphur diesel fuel. NOx-reduction has been measured as a function of engine load, engine speed, in-cylinder fuel injection timing, exhaust gas temperature, and exhaust gas recirculation. Over 60% conversion to N2 has been achieved at exhaust gas temperatures around 290°C.

Control of NOx and Particulate Matter (PM) emissions from diesel engines remains a significant challenge. One approach to reduce both emissions simultaneously without fuel economy penalty is the reformed exhaust gas recirculation (REGR) technique, where part of the fuel is catalytically reacted with hot engine exhaust gas to produce a hydrogen-rich combustible gas that is then fed to the engine. On the contrary to fuel cell technology where the reforming requirements are to produce a reformate with maximized H2 concentration and minimized (virtually zero) CO concentration, the key requirement of the application of the exhaust gas fuel reforming technique in engines is the efficient on-demand generation of a reformate with only a relatively low concentration of hydrogen (typically up to 20%).

Particulate Emissions from Homogeneous Charge Compression Ignition (HCCI) combustion are routinely assumed to be negligible. It is shown here that this is not the case when HCCI combustion is implemented in a direct injection gasoline engine. The conditions needed to sustain HCCI operation were realized using the negative valve overlap method for trapping high levels of residual exhaust gases in the cylinder. Measurements of emitted particle number concentration and electrical mobility diameter were made with a Cambustion DMS500 over the HCCI operating range possible with this hardware. Emissions of oxides of nitrogen, carbon monoxide and unburned hydrocarbons were also measured. These data are presented and compared with similar measurements made under conventional spark ignition (SI) operation in the same engine. Under both SI and HCCI operation, a significant accumulation mode was detected with particle equivalent diameters between 80 and 100 nm.

The aims of this study are to investigate the responses of a Hybrid III dummy and a human body model in rollover crashes of an SUV, and to assess the effect of seat belts on occupant kinematics in rollover events. A SAEJ2114 rollover test of a 1994 Ford Explorer for two front row dummies with an inflatable tubular structure (ITS) is reconstructed and validated in MADYMO. By removing the ITS, the simulations of the Hybrid III dummy occupants with and without seat belts are obtained. By replacing the dummy models with human body models, with and without seat belts, two other combinations are also modelled. The kinematics and injury risks of two kinds of occupant models are compared and evaluated. Significant differences exist in the motions, and injury levels of the dummies and human body models with and without seat belts. Seat belts can significantly mitigate against occupant ejection.

Particulate Matter (PM) emissions are of increasing importance, as diesel emissions legislation continues to tighten around the world. Diesel PM can be controlled using Diesel Particulate Filters (DPFs), which can effectively reduce the level of carbon (soot) emissions to ambient background levels. The Johnson Matthey Continuously Regenerating Trap (CRT®) [1], which will be referred to as the Continuously Regenerating DPF (CR-DPF) for the remainder of this paper, has been widely applied in Heavy Duty Diesel (HDD) applications, and has been proved to have outstanding field durability [2]. To widen the potential application of this system, addition of a platinum based catalyst to the DPF has been shown to lead to a higher PM removal rate under passive regeneration conditions, using the NOx contained in the exhaust gases.

A one-dimensional model of a NOx trap system was developed to describe NOx storage during the lean operation, and NOx release and subsequent reduction during the rich regeneration process. The development of a NOx trap model potentially enables the optimisation of catalyst volume, precious metal loading, substrate type and regeneration strategy for these complex systems. To develop a fundamental description of catalytic activity, experiments were conducted to investigate the key processes involved in isolation (as far as possible), using a Pt/Rh/BaO/Al2O3 model catalyst. A description of the storage capacity as a function of temperature was determined using NOx breakthrough curves and the storage portion of more dynamic lean-rich cycling experiments. NOx breakthrough curves were also used for determination of rate of NOx storage. Kinetics for NOx reduction, as well as CO and HC oxidation, were determined using steady state reactor experiments.

In recent years in the United Kingdom, dual-fuelled vehicles incorporating Liquid Petroleum Gas (LPG) have become more prevalent, as there are the perceived benefits of reduced fuelling costs, whilst also reducing the harmful emissions that effect air quality and climate change. In 2001, over 75,000 vehicles were registered as being powered by LPG and it is estimated that nearly 250,000 conversions were made to UK cars by the end of 2004. It is considered that the world population of such vehicles is in the order of 5 million vehicles, 2 million of which are being driven within EU countries.1 This paper will therefore examine the incidence of car fires in the area covered by Hereford and Worcester Fire and Rescue Service (HWFRS) in the UK. The data was used to establish the travel time for fire pumps to such incidents, the amount of time those units were detained at the scene and the possible cause of the fires themselves.